I think that drawing an Xline with Polar Tracking is tricky until you know what you are looking out for. Drawing an ordinary line would be much easier.
First of all, set up Polar Tracking by right clicking on the POLAR tab at the bottom of the screen and choose Settings. In the Polar Angle measurement, I use Relative to last segment. You can enter any Increment angle, but 45° is enough for me.
Polar Tracking displays temporary alignment paths defined by the polar angles you specify. As you move the cursor, when you get to a specified angle, a small cross appears at the cursor and the alignment path extends beyond the cursor. When you see this alignment path, you can pick the length of your line or enter it at the keyboard. Drawing a Xline is more difficult because the Xline is on top of the alignment path and you can only see the cross at the cursor.
Practice makes perfect, but when you can use it, Polar Tracking is most useful.