I modified some of the paper sizes to suit (I uses An Expand paper because I don't otherwise use the)...
Go to page setup, select Dwg to PDF plotter and then properties
Under 'Use-Defined Paper Sizes and Calibration' choose modify Standard Paper Sizes (though you can also go and create a Custom paper Size), and then choose the paper size in the box below, click modify and there you can set the margins, mine are set at 0. Click finish and then repeat for all the paper sies.
I used the standard paper sizes since I use a plotting list - and it is easier to use if I use a standard paper size.
Then when it comes to plotting, just choose your modified paper size